Hi,
There are probably tons of websites to give advice, but I think you should check out the books "Making Faces" and "Face Forward" by Kevin Aucoin.
Both seem really great at basic make up and Face Forward actually has several transformations.(male/females becoming famous models or stars)
Anyway, just a thought. Check out a bookstore or library.
Most guys are pretty bad at makeup in the beginning-it can take years to learn that less is more, subtle is sexy, and how to use your own features to best advantage. (or find a friend thats good at it and can teach you)
Good luck, and have fun!
VL