Logically I'd say no, a post op girl cannot produce sperm. Sperm is a mixture of semen produced by the testicles, and a secretion from the prostate gland. Your castrated ladyboy friend doesn't have testicles, but does still have her prostate, so still can produce some liquid.
Post op girls (I think) don't have a prostate anymore either, so wouldn't be able to ejaculate anything.
If someone knows more about the subject, please correct me if I'm wrong
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